User canceled primary password entry
Upload image file with the file dialog or by dragging and dropping images onto the dashed region
Have you used Zotero previously on this Mac, or have you transferred files from another Mac where you used it?
Can you make a ZIP of your Zotero profile folder and email it to support@zotero.org with a link to this thread?
After that, try deleting key4.db and logins.json and then restarting Zotero. But please do send first if you can.