Not syncing...can't log in to my account online
I tried to use my Chrome plug in to save an article without Zotero open. I received a notification that my account was not set to sync online. When I open Zotero preferences on the desktop app, it says that my account is set to sync (All Libraries). I tried logging in with that user name and was unable to do so. I asked for an email to reset my password but haven't received one. Any other way to reset my login info?
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Don't do anything else until we tell you to — it's sounds like you're trying all sorts of unrelated things that are making this much more complicated.
Here's the real question though - it looks like my Zotero desktop was set up in the past to sync online, but not I've forgotten the password to that online account. What alternatives do I have to sign into that account?
If you're seeing the Zotero login page when trying to save from your browser, it means that you don't have the Zotero app open (or the Zotero Connector can't talk to it). You always want to have the Zotero app open when saving as long as you're on a computer where you can install the app.
For resetting your password, generally if you don't receive an email it's because it went to your spam folder. (It looks like you've since deleted your account here, which was definitely not the right thing to do if you were syncing with this account…)