Storing data on a NAS

What will be the best method to store Zotero data (about 100GB of pdf's) on a NAS with no local storage of data? I've read about linked files, but am fuzzy on how that will work. I do have a mounted network share that I could use. Is this an optimal way to go about it?
I did manage to setup a data sync with WebDAV on a NextCloud instance, but still have local files.
The data is stored in folders with an ID. Is this necessary, ideally would love to have just one folder with correctly named pdf files. Possible?
Thanks much, searched but didn't find an answer.
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