Error report ID: 546176415
Issue resolved.
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1. In the Zotero Help menu, go to Debug Output Logging and select Enable.
2. Refresh the page that you are saving in Chrome and attempt to save it. Wait until the save process finishes fully, including all attachments.
3. Before doing anything else, return to Zotero Help → Debug Output Logging and click Submit Output, which will disable logging and submit the output to zotero.org. A window should pop up containing a Debug ID. Click “Copy to Clipboard” and paste the Debug ID into this forum thread.
You can try to fix the damage with the DB Repair Tool, or, if this was in cloud storage, from an earlier version of zotero.sqlite. If that doesn't work, and your data is all online, you can just delete the zotero.sqlite file (or move it somewhere temporarily for backup) with Zotero closed and then reopen Zotero and sync to pull down your library.