Chrome Connector - problem having two accounts?

I am quite new to Zotero and I hope someone can help me:

Is it a problem using two different Zotero accounts on the same computer? I am trying to save some journal articles in one of the accounts using the Chrome Connector, but when I click "save" it saves them in the other account library, that is the wrong one which I am not supposed to be connected to at the moment. I am only connected to Zotero through the browser login by the way.

Do I have to do something to make the Chrome Connector connect to the right account?
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