Zotero 3.0 for Firefox vs. Zotero Standalone
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I'll hope to upgrade for the record if i go onto a PhD, just don't know if i can justify it until then because of low funds (but i definitely think it is a service worth paying for as much as possible, it's such an amazing program!!)
http://www.zotero.org/support/sync
whether you use ZFF or ZSA has no impact on accessibility across different computers. People get confused by the fact that one is a browser add-on, but Zotero for Firefox is in no way more "online" or "cloud-based" than the Standalone version.
So, a year and a half later, any tips or warnings for someone who wants to do use the same strategy -> use Zotero Firefox (ZFF) when getting citations from online sources and then switch to Zotero Stand Alone (ZSA) when working on a Word document?
While it makes relatively little difference, it's recommended to keep ZSA closed when gathering citations in Firefox - on some few sites you'll get better results, mostly you're more likely to get PDFs attached.
The only reason to not use ZFF and use ZSA instead when working in Word is to make Firefox run smoother. This shouldn't be a problem anyway with relatively small libraries (probably < 5000 references) on a not-too-ancient computer.
Having said that, switching between ZSA and ZFF should be fairly seamless if you have them configured correctly (i.e. you cannot open Zotero in Firefox and Zotero Standalone at the same time). You would just need to either close or open ZSA.
There have been some reports of the URL bar icon not showing up in Firefox if ZSA or Firefox are started first (don't recall which), but we never got to the bottom of it, so if you encounter this, please report it and we can further troubleshoot it.
Jonathan Franzen actually tapes the ethernet port of his computer when he writes. Using Standalone instead of Firefox is the light version of that.