Using 2 different accounts

I have a library set up a few years ago and it runs fine. I just set up a second separate account
as I do not want to run 2 libraries under the same profile. Running current version of Zotero on Win 11. I do not get a sign in credentials display when using the app and it defaults to my older library when it opens.
How do I get to use the new account credentials with the app to set up a new independent library?
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