Zotero Standalone for mac won't start from the boot volume

When I try to launch Zotero Standalone 3.0.3 for mac on a macpro running Mac OS X 10.6.8, by double clicking it at Application folder, it immediately crashes. The console log shows:
12/03/19 16:17:55 [0x0-0x46046].org.zotero.zotero[582] Could not find the Mozilla runtime.
12/03/19 16:17:55 com.apple.launchd.peruser.501[144] ([0x0-0x46046].org.zotero.zotero[582]) Exited with exit code: 1

Strangely, if I copy that Zotero to a different volume such as another partition or DiskImage, somehow I can launch it without problem.
I'd appreciate any input on the issue, although its just a matter of convenience.

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